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Substituent effects on the stability of carbodications

✍ Scribed by Winn Peebles; Richard M. Pagni; Robert C. Haddon

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 230 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99109-3

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✦ Synopsis

Sunmary: Disubstituted phenalenyl cations undergo deuterium exchange in CF3SO30 by a mechanism that involves protonation of the ring to form carbodications. The effect of a variety of substituents on this process is reported.

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