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Substituent effects on the decomposition of chemiluminescent tricyclic aromatic dioxetanes

โœ Scribed by Sun, Chung-Wen; Chen, Shun-Chi; Fang, Tai-Shan


Book ID
121408361
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
672 KB
Volume
29
Category
Article
ISSN
1522-7235

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Substituent effects on the decomposition
โœ A.Paul Schaap; Steven D. Gagnon; K.A. Zaklika ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

Rates of decomposition for 1,2-dloxetanes obtained from addition of singlet oxygen to substituted 2,3-diaryl-1,4-dioxenes have been found to obey a Hammett relationship with p+ = -0 24 (n = 15, r = 0.92). The results are taken as support for a brradrcal mechanism. The chemlluminescent decompositio