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Solvent effects on the chemiluminescent decomposition of tetramethyl-1,2-dioxetane. Competitive dark pathways

โœ Scribed by Wilson, Therese.; Landis, Michael E.; Baumstark, Alfons L.; Bartlett, Paul D.


Book ID
120523127
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
281 KB
Volume
95
Category
Article
ISSN
0002-7863

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Substituent effects on the decomposition
โœ A.Paul Schaap; Steven D. Gagnon; K.A. Zaklika ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

Rates of decomposition for 1,2-dloxetanes obtained from addition of singlet oxygen to substituted 2,3-diaryl-1,4-dioxenes have been found to obey a Hammett relationship with p+ = -0 24 (n = 15, r = 0.92). The results are taken as support for a brradrcal mechanism. The chemlluminescent decompositio