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Substituent effects on the decomposition of 1,2-dioxetanes

โœ Scribed by Zaklika, K. A.; Thayer, Arthur L.; Schaap, A. Paul


Book ID
125975487
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
399 KB
Volume
100
Category
Article
ISSN
0002-7863

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Rates of decomposition for 1,2-dloxetanes obtained from addition of singlet oxygen to substituted 2,3-diaryl-1,4-dioxenes have been found to obey a Hammett relationship with p+ = -0 24 (n = 15, r = 0.92). The results are taken as support for a brradrcal mechanism. The chemlluminescent decompositio

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