Substituent effects on the decomposition
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A.Paul Schaap; Steven D. Gagnon; K.A. Zaklika
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Article
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1982
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Elsevier Science
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French
โ 225 KB
Rates of decomposition for 1,2-dloxetanes obtained from addition of singlet oxygen to substituted 2,3-diaryl-1,4-dioxenes have been found to obey a Hammett relationship with p+ = -0 24 (n = 15, r = 0.92). The results are taken as support for a brradrcal mechanism. The chemlluminescent decompositio