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Decomposition of 1,2-dioxetane

✍ Scribed by Charles W. Eaker; Juergen Hinze


Publisher
Springer
Year
1975
Tongue
English
Weight
425 KB
Volume
40
Category
Article
ISSN
1432-2234

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Two spiro [1,2-dioxetane-3,6'-benzo(c)chromene]s bearing a t-butyldimethylsiloxy as a trigger at the 10'-or 2'-position were synthesized. On treatment with tetrabutylammonium fluoride in DMSO at 25Β°C, the 10'-siloxyspiro[1,2-dioxetane-3,6'benzo(c)chromene] decomposed rapidly to afford a flash of blu