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Substituent effects in the reaction between benzaldehydes and polyacrylonitrile radicals

✍ Scribed by L.N. Patnaik; N.C. Samal; M. Senapati; R. Mishra; M.K. Rout

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
133 KB
Volume
19
Category
Article
ISSN
0014-3057

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✦ Synopsis

The effects of substituents on the reaction of benzaldehydes with polyacrylonitrile radicals have been studied in terms of the multiparameter equations based on Swain and Lupton's Field and Resonance (F and R) components with the unique positional weighting factors f and r developed by Williams and Norrington. From the nature of the reaction constants, a polar transition state has been postulated.

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