## Abstract The additivity of chloro and hydroxy substituent effects on the formyl proton spin‐spin coupling constants with the __meta__ ring proton, ^5^__J__(HH), has been tested with 15 chlorinated benzaldehydes and hydroxybenzaldehydes by multiple linear regression analysis. No general additivit
Additive of substituent effects on the chemical shift of the formyl proton in disubstituted benzaldehydes
✍ Scribed by H. O. Castañeda; R. H. Contreras; D. G. de Kowalewski
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 153 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
An additivity relationship of substituent effects on the formyl proton chemical shift has been tested with ten disubstituted benzaldehydes. In most cases it is found that the formyl proton chemical shift, extrapolated to infinite dilution in nitromethane, is in good agreement with that calculated using the additivity relationship.
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