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Determination of substituent chemical shifts in the proton resonance spectra of the porphyrins

✍ Scribed by Raymond J. Abraham; Fahimeh Eivazi; R. Nayyir-Mazhir; Harry Pearson; Kevin M. Smith

Publisher: John Wiley and Sons
Year: 1978
Tongue: English
Weight: 284 KB
Volume: 11
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270110116

No coin nor oath required. For personal study only.

✦ Synopsis

Reproducible proton chemical shifts in the porphyrin series are obtained when the spectrum is measured in chloroform using the zinc (11) complex of the porphyrin in the presence of an excess of pyrrolidine. This method is specifically demonstrated for the case of 2,4-dicyanodeuteroporphyrin-M dimethyl ester which, as the free base, shows dramatic effects due to aggregation phenomena. The shifts obtained using the zinc (11) complex plus oyrrolidine method, which allow compilation of substituent cheniical shifts in the porphyrin series, are shown to be the same as the less easily accessible infinite dilution shifts of the porphyrin free bases.

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