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Substituent effects on the lifetime and fluorescence of excited diphenylmethyl radicals in solution

✍ Scribed by D. Weir; J.C. Scaiano

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 305 KB
Volume: 128
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80316-5

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✦ Synopsis

The room-temperature lifetimes of ring-substituted excited diphenylmethyl radicals have been shown to correlate well with the energy gap between the fluorescent lowest excited doublet and the ground state. Attempts to correlate the lifetimes with Hammett constants were unsuccessful.

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