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Absorption, fluorescence, lifetime and reactivity of excited di(p-methylphenyl)methylene in solution

✍ Scribed by Linda J. Johnston; J.C. Scaiano

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 356 KB
Volume: 116
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80136-6

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✦ Synopsis

The absorpuon spsuum. fluorescence and kineucs of cl(p-melhylphenyl)methyleae have been exarmned uang laser photolysis k&niques In acetonitrile tie exerted carbene has a lifetime of 5 6 ns at room temperature and reacts wrth carbon letrachlonde wltb k = 1.1 X IO9 M-' s-l-The absorption of the exated carbene shows h _ = 370 nm, wfule IS fluore5ccnce

peaks at = 517 nm.

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