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Substituent Effects in the Interconversion of Phenylcarbene, Bicyclo[4.1.0]hepta-2,4,6-triene, and 1,2,4,6-Cycloheptatetraene

✍ Scribed by Geise, C. Michael; Hadad, Christopher M.

Book ID
126977762
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
119 KB
Volume
67
Category
Article
ISSN
0022-3263

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## Abstract 2‐(__tert__‐Butyl)‐3,7‐dehydrotropone (7‐(__tert__‐butyl)bicyclo[3.2.0]hepta‐1(7),2,4‐trien‐6‐one; **1**) was found to dimerize reversibly to **2A** by [2 + 4]‐cycloaddition/cycloreversion reaction. The equilibrium lies on the side of the highly strained dimer **2A** in the solid state,