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Photoequilibration of 2-naphthylcarbene and 2,3-benzobicyclo[4.1.0]hepta-2,4,6-triene

✍ Scribed by Albrecht, Steven W.; McMahon, Robert J.

Book ID: 126445376
Publisher: American Chemical Society
Year: 1993
Tongue: English
Weight: 543 KB
Volume: 115
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00056a005

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## Abstract 2‐(__tert__‐Butyl)‐3,7‐dehydrotropone (7‐(__tert__‐butyl)bicyclo[3.2.0]hepta‐1(7),2,4‐trien‐6‐one; **1**) was found to dimerize reversibly to **2A** by [2 + 4]‐cycloaddition/cycloreversion reaction. The equilibrium lies on the side of the highly strained dimer **2A** in the solid state,