Photochemistry of 4-cyano-2,3-benzobicyclo[4.2.0]octa-2,4,7-triene
โ Scribed by Bender, Christopher Owen; Dolman, Douglas; Tu, Noah
- Book ID
- 125969163
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 774 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Two new crystaZZine bicyclo[4.2.OIocta-2,4,7-trienes have been prepared by photodecarbonylation of the a,v$q+L$; structures confirmed by tricyc~o[4.2.1.0 2~5]nona-3,7-dien-9-ones and their The tztle compounds alI undergo thermal ring opening to cyclooctatetmenes, but photolysis is substituent depend
Derivatives of bicyclo[4.2.O]octa-2,4,'7-triene (I) have been invoked as intermediates in the light-induced formation of cycle-octatetraenes from certain acetylenes and benzene (1,2,3) or benzonitrile (4) as well as in the photochemical synthesis of 1:l adducts[e.g., (II)1 from tolan (diphenylacetyl