Suhstituent effects an complex formation between variously substituted metallodeuteroporphyrins with filled 12~ orbitals and extraplanar hgand(s) ean be correlated by Hammett freeenergy plots. The slopes of these plots are positive and the correlation is high with substituent constants typical of re
โฆ LIBER โฆ
Substituent effects in the electroreduction of porphyrins and metalloporphyrins
โ Scribed by Giraudeau, A.; Callot, H. J.; Jordan, Joseph; Ezhar, I.; Gross, Maurice
- Book ID
- 121205289
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 750 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0002-7863
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Porphyrins and metalloporphyrins provide an extremely versatile nanometer-sized building block for the control of materials properties. Films, solids and microporous solids have been explored as field-responsive materials (i.e. interactions with applied electric, magnetic or electromagnetic fields)