is presented of the status of quantum chemical studies of porphyrins and related molecules.
The materials chemistry of porphyrins and metalloporphyrins
β Scribed by Kenneth S. Suslick; Neal A. Rakow; Margaret E. Kosal; Jung-Hong Chou
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 218 KB
- Volume
- 04
- Category
- Article
- ISSN
- 1088-4246
No coin nor oath required. For personal study only.
β¦ Synopsis
Porphyrins and metalloporphyrins provide an extremely versatile nanometer-sized building block for the control of materials properties. Films, solids and microporous solids have been explored as field-responsive materials (i.e. interactions with applied electric, magnetic or electromagnetic fields) and as βchemo-responsiveβ materials (i.e. interactions with other chemical species as sensors or for selective binding or catalysis).
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Common methods available for the preparation of useful porphyrins from naturally derived heme and by total synthesis from monopyrroles are presented. Such porphyrins can be used for numerous reactivity and structural modification studies of the type which will be presented in minisymposia (including
A series of thiol-derivatized porphyrins and the corresponding cobalt and zinc complexes were synthesized from 5-(p-aminophenyl)-10,15,20-triphenylporphyrin (H 2 TPP-NH 2 ), and 5Ξ±,15Ξ±-bis(o-aminophenyl)porphyrin (H 2 DPE-(NH 2 ) 2 ). These derivatized porphyrins have a different number of thiol app
Recent advances in the electron transfer chemistry of metalloporphyrins and related metal complexes are reviewed briefly by focusing not only on the electron transfer processes but also on the subsequent chemical processes associated with electron transfer processes of metalloporphyrins and related