Solvent effects in molecular complexes of porphyrins and metalloporphyrins
โ Scribed by S. H. Mehdi; D. A. Brisbin; W. A. E. McBryde
- Publisher
- Springer US
- Year
- 1975
- Tongue
- English
- Weight
- 536 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0095-9782
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Suhstituent effects an complex formation between variously substituted metallodeuteroporphyrins with filled 12~ orbitals and extraplanar hgand(s) ean be correlated by Hammett freeenergy plots. The slopes of these plots are positive and the correlation is high with substituent constants typical of re
A series of thiol-derivatized porphyrins and the corresponding cobalt and zinc complexes were synthesized from 5-(p-aminophenyl)-10,15,20-triphenylporphyrin (H 2 TPP-NH 2 ), and 5ฮฑ,15ฮฑ-bis(o-aminophenyl)porphyrin (H 2 DPE-(NH 2 ) 2 ). These derivatized porphyrins have a different number of thiol app