Styrene copolymerization using a metallocene-MAO initiator system. Homo- and copolymerization of styrene with some cycloalkenes
✍ Scribed by Franco M. Rabagliati, Daniela E. Yañez, Daniel Canales, Raúl Quijada…
- Book ID
- 120778503
- Publisher
- Springer
- Year
- 2013
- Tongue
- English
- Weight
- 495 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0170-0839
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📜 SIMILAR VOLUMES
The copolymerization of styrene (St) with a styrene-terminated polyisoprene macromonomer (SIPM) by a nickel(II) acetylacetonate [Ni(acac) 2 ] catalyst in combination with methylaluminoxane (MAO) was investigated. A SIPM with a high terminal degree of functionalization and a narrow molecular weight d
Copolymerization of ethylene with a symmetrical diene, namely, 2,5-norbornadiene was studied using a homogeneous metallocene/MAO catalyst system. Copolymerizations were found to occur exclusively through one of the two equally reactive endocyclic double bonds with Cp 2 ZrCl 2 , (buCp) 2 ZrCl 2 and E
## Abstract The free‐radical copolymerization of methyl acrylate with styrene initiated by triphenylstibonium 1,2,3,4‐tetraphenylcyclopentadienylide under nitrogen blanket at (60 ± 0.1)°C in 1,4,dioxane for 2 h has been carried out. The kinetic expression is __R~p~__ ∝ [I]^0.14^ [MA]^0.70^ [Sty]^0.