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Copolymerization of methylmethacrylate with styrene using triphenylbismuthoniumylide as radical initiator

✍ Scribed by Radha Bajpai; A. K. Srivastava


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
220 KB
Volume
80
Category
Article
ISSN
0021-8995

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Copolymerization of methyl acrylate with
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## Abstract The free‐radical copolymerization of methyl acrylate with styrene initiated by triphenylstibonium 1,2,3,4‐tetraphenylcyclopentadienylide under nitrogen blanket at (60 Β± 0.1)Β°C in 1,4,dioxane for 2 h has been carried out. The kinetic expression is __R~p~__ ∝ [I]^0.14^ [MA]^0.70^ [Sty]^0.

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## Abstract Copolymerization of styrene (St) and methyl methacrylate (MMA) was carried out using 1,1,2,2‐tetraphenyl‐1,2‐bis (trimethylsilyloxy) ethane (TPSE) as initiator; the copolymerization proceeded via a β€œliving” radical mechanism and the polymer molecular weight (__M__~__w__~) increased with