Isospecific copolymerization of styrene and a styrene-terminated polyisoprene macromonomer with the Ni(acac)2/MAO catalyst

✍ Scribed by Kazunobu Senoo; Kiyoshi Endo

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 112 KB
• Volume: 38
• Category: Article
• ISSN: 0887-624X
• DOI: 10.1002/(sici)1099-0518(20000415)38:8<1241::aid-pola7>3.0.co;2-o

✦ Synopsis

The copolymerization of styrene (St) with a styrene-terminated polyisoprene macromonomer (SIPM) by a nickel(II) acetylacetonate [Ni(acac) 2 ] catalyst in combination with methylaluminoxane (MAO) was investigated. A SIPM with a high terminal degree of functionalization and a narrow molecular weight distribution was used for the copolymerization of St. The copolymerization proceeded easily to give a high molecular weight graft copolymer. After fractionation of the resulting copolymer with methyl ethyl ketone, the insoluble part had highly isotactic polystyrene in the main chain and polyisoprene in the side chain. Lowering the MAO/Ni molar ratio and the polymerization temperature were favorable to producing isospecific active sites.