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Study of the Nucleophilic Addition of Alcoholates on cis -Fe(R)(R‘)(CO) 3 L (R, R‘ = Alkyl, Alkoxycarbonyl, Alkyloxalyl; L = CO, P(OEt) 3 ) and the First Characterization of a Tris(alkoxycarbonyl) Complex: K[Fe(CO 2 tBu) 3 (CO) 3 ]

✍ Scribed by Sellin, Murielle; Luart, Denis; Salaün, Jean-Yves; Laurent, Pascale; Toupet, Loïc; des Abbayes, Hervé


Book ID
127277179
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
344 KB
Volume
15
Category
Article
ISSN
0276-7333

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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__