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Synthesis, characterization, and electrochemistry of the mono- and bi-dentate xanthate complexes η5-C5R5Fe(CO)(η1-SC(S)OEt)L and η5-C5R5Fe(η2-S2COEt) L (R = H, Me; L = PBu3, PPh3, P(OEt)3, P(OPh)3)

✍ Scribed by M. Morán; I. Cuadrado; J.R. Masaguer; J. Losada


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
960 KB
Volume
335
Category
Article
ISSN
0022-328X

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Synthesis and Structure of the First η3-
✍ Lothar Weber; Gabriel Noveski; Ulrich Lassahn; Hans-Georg Stammler; Beate Neuman 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 1 views

## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C