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Nucleophilic addition to (.eta.6(alkylbenzene)Cr(CO)3) complexes. Dependence of regioselectivity on the size of the alkyl group and the reactivity of the nucleophile

✍ Scribed by Semmelhack, M. F.; Garcia, J. L.; Cortes, D.; Farina, R.; Hong, R.; Carpenter, B. K.


Book ID
127271019
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
437 KB
Volume
2
Category
Article
ISSN
0276-7333

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Observations on regioselectivity during
✍ Anthony J. Pearson; Manoj Babu πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 215 KB

Addition of carbon nucleophiles, such as phenylmagnesium bromide, to isoprene-Mo(CO)2Tp (Tp = hydridotris(l-pyrazolyl)borato), can proceed with excellent regiocontrol, predominantly at the diene terminus remote from the 2-methyl substituent. In contrast to the corresponding cyclopentadienyl complex,