The effect of a chain-transfer agent (CTA) on the kinetics and molecular weight distribution of the methyl methacrylate/butyl acrylate semicontinuous emulsion polymerization was investigated. The dodecanethiol had a slight effect on the reaction rate but significantly affected the secondary nucleati
Study of the kinetic aspects of emulsion copolymerization of butyl acrylate with the methacrylic ester of α-hydroxyethyl-tert-butyl peroxide
✍ Scribed by V.N. Pavlyuchenko; Z.M. Alekseyeva; S.S. Ivanchev
- Book ID
- 118967040
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 483 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0032-3950
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Butyl acrylate (BA) and methyl methacrylate (MMA) have been copolymerized in a 3 mol/L benzene solution using 2,2 -azobis(isobutyronitrile) (AIBN) as initiator over a wide composition and conversion range. The overall copolymerization parameter k p /k 1/2 t and the composition of the copolymer forme
## Abstract Free‐radical copolymerization at 50°C of butyl acrylate with methyl methacrylate was carried out in benzene solution using 3 and 5 mol/L as the overall concentration of monomers. Both the reactivity ratios and the rate coefficients of copolymerization are affected by the total monomer c