𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Termination mechanism in the anionic copolymerization of methyl methacrylate and tert-butyl acrylate

✍ Scribed by Jacobs, Christian; Varshney, Sunil K.; Hautekeer, Jean Paul; Fayt, Roger; Jerome, Robert; Teyssie, Philippe

Book ID
127132155
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
265 KB
Volume
23
Category
Article
ISSN
0024-9297

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Back-Biting Termination in Methyl Methac
Back-Biting Termination in Methyl Methacrylate/tert-Butyl Acrylate Anionic Block Copolymerization
✍ Eva ČadovΓ‘; JiΕ™Γ­ Dybal; Jaroslav KΕ™Γ­ΕΎ; Petr Vlček; Miroslav Janata; LudΔ›k Toman πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 294 KB

## Abstract The product of spontaneous termination formed after addition of one or two __t__‐BuA units onto living PMMA chains in the MMA__/t__‐BuA block copolymerization was isolated and characterized by SEC, UV, FT‐IR, Raman and NMR spectroscopy. It appears as a low‐molecular‐weight peak in SEC e

Termination kinetics in free-radical bul
Termination kinetics in free-radical bulk terpolymerization β€” the systems methyl acrylate – butyl acrylate – dodecyl acrylate and methyl methacrylate – butyl methacrylate – dodecyl methacrylate
✍ Michael Buback; Christopher Kowollik πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 93 KB πŸ‘ 2 views

Termination rate coefficients, k t , for the terpolymerization of mixtures containing the three acrylates: methyl, butyl, and dodecyl acrylate or the corresponding members of the methacrylate family: methyl, butyl, and dodecyl methacrylate, have been measured via the single pulse (SP)-PLP technique.

Catalytic Chain Transfer Copolymerizatio
Catalytic Chain Transfer Copolymerization of Methyl Methacrylate and Butyl Acrylate
✍ Sebastiaan C. J. Pierik; Alex M. van Herk πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 221 KB

## Abstract In this work it is shown that catalytic chain transfer is a very efficient way of controlling molecular weight in the copolymerization of methyl methacrylate (MMA) and butyl acrylate (BA). The experimental data are compared to a previously developed model based on copolymerization kinet