𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Study of the fragmentation mechanism of novel functionalized macrocycles by Fourier transform ion cyclotron resonance mass spectrometry

✍ Scribed by Hui Chen; Da-Ming Du; Wen-Ting Hua; Meiyu He; Bin Xin

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
123 KB
Volume
38
Category
Article
ISSN
1076-5174

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Liquid secondary ion mass spectrometry (L‐SIMS) of six new functionalized macrocycles was investigated. All six compounds yielded abundant fragment ions and protonation molecular ions [M + H]^+^ under L‐SIMS conditions. The proposed fragmentation mechanisms were supported by high‐resolution accurate mass data from Fourier transform ion cyclotron resonance mass spectrometric and MS^n^ experiments on using sustained off‐resonance irradiation collision‐induced dissociation. Copyright Β© 2003 John Wiley & Sons, Ltd.

πŸ“œ SIMILAR VOLUMES

Laser Ablation of Silica: Study of Induc
Laser Ablation of Silica: Study of Induced Clusters by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
✍ Lafargue, P. E.; Gaumet, J. J.; Muller, J. F.; Labrosse, A. πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 748 KB

Silica clusters were produced by laser vaporizatian of three difierent silica compounds and the ionized species were analysed by using Fourier transform ion cyclotron resonance mass spectrometry. Using a wavelength of 248 nm, negativeion mass spectra of E2, Merck and Stober's silica showed different

Generation of hydrogen radicals for reac
Generation of hydrogen radicals for reactivity studies in Fourier transform ion cyclotron resonance mass spectrometry
✍ Plamen A. Demirev πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 69 KB πŸ‘ 2 views

An efficient technique for generation of H\* (D\*) radicals in Fourier transform ion cyclotron resonance (FTICR) mass spectrometry is described. The method allows the probing of the reactivity of gas-phase H\* radicals towards various ions isolated in the cell of an FTICR mass spectrometer. Results

Study of gas-phase molecular recognition
Study of gas-phase molecular recognition using Fourier transform ion cyclotron resonance mass spectrometry (FTICR/MS)
✍ David V. Dearden; Yongjiang Liang; Jeremy B. Nicoll; Katherine A. Kellersberger πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 183 KB

## Abstract The application of Fourier transform ion cyclotron resonance (FTICR) mass spectrometry to the quantitative study of molecular recognition in the gas phase is reviewed. Because most quantitative measurements are dependent on accurate determination of the pressure of a neutral reagent, me

Solvation of acylium fragment ions in el
Solvation of acylium fragment ions in electrospray ionization quadrupole ion trap and Fourier transform ion cyclotron resonance mass spectrometry
✍ Ziqiang Guan; Jerrold M. Liesch πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 330 KB

## Abstract In electrospray ionization (ESI) quadrupole ion trap and Fourier transform ion cyclotron resonance mass spectrometry, certain fragment ions (e.g. acylium ions) generated either during the ion transportation process (in the source interface region) or in the ion trap are found to undergo

Identification of Human Liver Diacetyl R
Identification of Human Liver Diacetyl Reductases by Nano-Liquid Chromatography/Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
✍ Yorihisa Tanaka; Ikuya Sato; Chisaki Iwai; Toshiyuki Kosaka; Toshihiko Ikeda; Ta πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 238 KB

Several forms of diacetyl-reducing enzyme were found to exist in the human liver cytosol. Three (DAR-2, DAR-5, and DAR-7) of them were purified as a single band on SDS-PAGE by a combination of a few kinds of column chromatographies. The in-gel tryptic digests of the purified enzymes were analyzed by