Study of Preferential Solvation in Binary Mixtures by Means of Frequency-Domain Fluorescence Spectroscopy
β Scribed by N. Kh. Petrov; D. E. Markov; M. N. Gulakov; M. V. Alfimov; H. Staerk
- Book ID
- 110335577
- Publisher
- Springer
- Year
- 2002
- Tongue
- English
- Weight
- 69 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1053-0509
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π SIMILAR VOLUMES
Using the picosecond spectra-streak method we monitored the dynamics of preferential solvation of a charge-transfer dipole in binary mixtures of solvents strongly different in dielectric constant. The observed slow (0.25-l ns) spectra1 red-shift of the charge-transfer (exciplex) fluorescence is cons
The preferential solvation of neutral and ionic organic species (phenol, nitroanilines, N-methylbutyramide, 1,4-dioxane, acetate and tetraalkylammonium ions) in binary solvent mixtures (aqueous CH 3 CN, DMSO, EtOH, 1-PrOH, CH 3 CON(CH 3 ) 2 ; CH 2 Cl 2 /Et 2 O; 1,4-dioxane/benzene; cyclohexane/THF)