𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Studies on the kinetics of imidazolium fluorochromate oxidation of some meta- and para-substituted anilines in nonaqueous media

✍ Scribed by D. S. Bhuvaneshwari; K. P. Elango

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
107 KB
Volume
38
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The imidazolium fluorochromate (IFC) oxidation of meta‐ and para‐substituted anilines, in seven organic solvents, in the presence of p‐toluenesulfonic acid (TsOH) is first order in IFC and TsOH and is zero order with respect to substrate. The IFC oxidation of 15 meta‐ and para‐substituted anilines at 299–322 K complies with the isokinetic relationship but not to any of the linear free energy relationships; the isokinetic temperature lies within the experimental range. The specific rate of oxidizing species‐anilines reaction (k~2~) correlates with substituent constants affording negative reaction constants. The rate data failed to correlate with macroscopic solvent parameters such as ε~r~ and E^N^~T~. A correlation of rate data with Kamlet–Taft solvatochromic parameters (α, β, π*) suggests that the specific solute–solvent interactions play a major role in governing the reactivity, and the observed solvent effects have been explained on the basis of solute–solvent complexation. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 38: 166–175, 2006

📜 SIMILAR VOLUMES

Solvent and substituent effects on the e
Solvent and substituent effects on the electrochemical oxidation of para- and meta-substituted anilines
✍ D. S. Bhuvaneshwari; K. P. Elango 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB 👁 2 views

## Abstract Electrochemical oxidation of 15 para‐ and meta‐substituted anilines in different mole fractions of water in 2‐methylpropan‐2‐ol has been investigated in the presence of 0.1 M sulfuric acid as a supporting electrolyte. The oxidation potential data of anilines correlate well with the Brow

Pyridiniumchlorochromate oxidations: Stu
Pyridiniumchlorochromate oxidations: Studies on the kinetics and substituent effect in the oxidation of aniline in nonaqueous systems
✍ G. P. Panigrahi; D. D. Mahapatro 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 375 KB

## Abstract Pyridiniumchlorochromate (PCC) oxidizes aniline and substituted anilines except nitro anilines smoothly in chlorobenzene–nitrobenzene mixtures in the presence of dichloroacetic acid. The reaction has unit dependence on each of the aniline, PCC, and dichloroacetic acid concentrations. El

Kinetics of oxidation of some meta- and
Kinetics of oxidation of some meta- and para-substituted phenyl methyl sulfoxides by chloramine-T in buffered ethanol–water
✍ K. Ganapathy; P. Jayagandhi 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 375 KB 👁 1 views

The kinetics of oxidation of methyl phenyl sulfoxide by chloramine-T (CAT) has been studied in buffered ethanol-water (1:l v/v) of pH 7.0. The reaction was found to follow no simple-order kinetics. A possible mechanism is suggested involving three rate-controlling steps: (1) the reaction between RNH

Kinetics of chlorination of some Ortho-,
Kinetics of chlorination of some Ortho-, Meta-, and Para-substituted phenols by N-chloro-3-methyl-2,6-diphenylpiperidin-4-one: A LFER study
✍ K. Ganapathy; An. Palaniappan 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 446 KB 👁 2 views

The kinetics of chlorination of a number of ortho-, meta-, and para-substituted phenols by N-chloro-3-methyl-2,6-diphenylpiperidin-4-one (NCP) in acid medium have been investigated. The reaction is of first order with respect to oxidant and the order with respect to the substrate varies depending o

Kinetics of oxidation of some ortho, met
Kinetics of oxidation of some ortho, meta, and para substituted S-phenylmercaptoacetic Acids by N-Chloro-3-Methyl-2,6-Diphenyl piperidin-4-one in buffered ethanol-water
✍ K. Ganapathy; S. Kabilan 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 354 KB 👁 2 views

The kinetics of oxidation of a number of ortho, meta, and para substituted S-phenylmercaptoacetic acids by N-Chloro-3-Metyl-2,6-Diphenylpiperidin-4-one (NCP) has been studied in buffered ethanol-water (75:25 v/v) of pH 5.46. The reaction is of first order each in [oxidant] and [substrate]. The rate