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Pyridiniumchlorochromate oxidations: Studies on the kinetics and substituent effect in the oxidation of aniline in nonaqueous systems

✍ Scribed by G. P. Panigrahi; D. D. Mahapatro

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
375 KB
Volume
14
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Pyridiniumchlorochromate (PCC) oxidizes aniline and substituted anilines except nitro anilines smoothly in chlorobenzene–nitrobenzene mixtures in the presence of dichloroacetic acid. The reaction has unit dependence on each of the aniline, PCC, and dichloroacetic acid concentrations. Electron‐releasing substituents accelerate the reaction, whereas electronwithdrawing groups retard the reaction, and the rate data obey Hammett's relationship. The reaction constant ρ is ‐3.75. Azobenzene and p‐benzoquinone have been obtained as products. The observed experimental data have been rationalized in terms of the formation of an intermediate complex involving PCC–amine undergoing a rapid decomposition to products.

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