The reaction rates of 2-chloro-3,5-dinitropyridine 1 with a series of arylthiolates 2a-h in methanol have been measured at 25Β°C. The products are the corresponding 2-thioaryl-3,5-dinitropyridine 3a-h. Good Hammett correlation with value Οͺ1.19 was obtained suggesting an elimination-addition mechanism
Kinetics of the reaction of 2-chloro-3,5-dinitropyridine with meta- and para-substituted anilines in methanol
β Scribed by Fatma El-Zahraa M. EL Hegazy; Soheir Z. Abdel Fattah; Ezzat A. Hamed; Saber M. Sharaf
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 63 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0894-3230
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