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STUDIES ON POLYPEPTIDES. II. THE PREPARATION OF α-AMINO ACID CARBOBENZOXYHYDRAZIDES

✍ Scribed by Hofmann, Klaus; Magee, Margaret Z.; Lindenmann, Adolf


Book ID
126265441
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
245 KB
Volume
72
Category
Article
ISSN
0002-7863

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Syntheses of a-fluoro-o-amino acid derivatives have been attempted from the viewpoints of their structural and biological interests. o-Amino esters were diazotised with i-AmONO or NaN02 to produce the corresponding diazo esters, which were treated with NBS and HF/pyridine to yield the a-bromo-a-fluo