Studies on methylatedβ-cyclodextrins and C60inclusion complexes
✍ Scribed by Dao-Dao Zhang; Ji-Wei Chen; Ying Yang; Rui-Fang Cai; Xiao-Liang Shen; Shi-Hui Wu
- Publisher
- Springer Netherlands
- Year
- 1993
- Tongue
- English
- Weight
- 368 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0923-0750
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AM1 semiempirical molecular orbital calculations have been performed Ž . on the inclusion complexes of -cyclodextrin -CD with methylated benzoic acids in two orientations, the ''head-first'' and ''tail-first'' positions. In the former, the CO H 2 group points toward the primary hydroxyls of the CD
The inclusion complexes of cyclomaltoheptaose (/3-CD) and /~-CD's 50% hydroxyethyl-substituted derivative (HE-/3-CD) with chlorogenic acid (CA) were studied with regard to temperature and water activity (all2 o = mole fraction = XH2 o = 0.8--0.99; 0.1 M Na phosphate buffer) utilizing first-derivativ