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STUDIES ON MACROCYCLIC DITERPENOIDS(XIV) - A Novel Total SYNTHESIS OF (±)-S-M

✍ Scribed by Xiangjun Yue; Yulin Li

Book ID
101761109
Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
397 KB
Volume
103
Category
Article
ISSN
0037-9646

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STUDIES ON MACROCYCLIC DITERPENOIDS (XV)
STUDIES ON MACROCYCLIC DITERPENOIDS (XV) - TOTAL SYNTHESIS OF (R)-(-)-CEMRENE-A
✍ Xiangjun Yue; Yulin Li 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 170 KB

## Abstract The total synthesis of (__R__)‐(‐)‐cembrene‐A was described in ∼29% overall yield from __E__‐geranyl acetone and (__R__)‐(+)‐limonene through ten steps by using the modified Wittig reaction and titanium‐induced intramolecular carbonyl coupling as key steps.