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Studies on macrocyclic diterpenoids. V. Synthesis of (±)-sarcophytol-A benzyl ether

✍ Scribed by Wei-Dong Li; Ying Li; Jian-Min Mao; Yu-Lin Li


Book ID
112060143
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
334 KB
Volume
11
Category
Article
ISSN
0256-7660

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STUDIES ON MACROCYCLIC DITERPENOIDS (XV)
✍ Xiangjun Yue; Yulin Li 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 170 KB

## Abstract The total synthesis of (__R__)‐(‐)‐cembrene‐A was described in ∼29% overall yield from __E__‐geranyl acetone and (__R__)‐(+)‐limonene through ten steps by using the modified Wittig reaction and titanium‐induced intramolecular carbonyl coupling as key steps.