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Studies on Highly Stereoselective Addition−Elimination Reactions of 3-(Methoxycarbonyl)-1,2-allen-4-ols with MX. An Efficient Synthesis of 3-(Methoxycarbonyl)-2-halo-1,3( Z )-dienes

✍ Scribed by Deng, Youqian; Jin, Xin; Ma, Shengming


Book ID
127383165
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
74 KB
Volume
72
Category
Article
ISSN
0022-3263

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Highly Regio- and Stereoselective Iodohy
✍ Zhenhua Gu; Youqian Deng; Wei Shu; Shengming Ma 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 91 KB 👁 2 views

## Abstract An efficient protocol for the highly regio‐ and stereoselective synthesis of 4‐(3′‐hydroxy‐2′‐iodoalk‐1′(__Z__)‐enyl)furan‐2(5__H__)‐one derivatives __via__ selective iodohydroxylation of non‐heteroatom‐substituted allenes, i.e., 4‐allenyl‐2(5__H__)furanones, has been developed. The reg