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Highly Regio- and Stereoselective Iodohydroxylation of Non-Heteroatom-Substituted Allenes: An Efficient Synthesis of 4-[3′-Hydroxy-2′-iodoalk-1′(Z)-enyl]-2(5H)-furanone Derivatives.

✍ Scribed by Zhenhua Gu; Youqian Deng; Wei Shu; Shengming Ma

Publisher
John Wiley and Sons
Year
2007
Weight
28 KB
Volume
38
Category
Article
ISSN
0931-7597

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Highly Regio- and Stereoselective Iodohy
Highly Regio- and Stereoselective Iodohydroxylation of Non- Heteroatom-Substituted Allenes: An Efficient Synthesis of 4-[3′-Hydroxy-2′-iodoalk-1′(Z)-enyl]-2(5H)-furanone Derivatives
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## Abstract An efficient protocol for the highly regio‐ and stereoselective synthesis of 4‐(3′‐hydroxy‐2′‐iodoalk‐1′(__Z__)‐enyl)furan‐2(5__H__)‐one derivatives __via__ selective iodohydroxylation of non‐heteroatom‐substituted allenes, i.e., 4‐allenyl‐2(5__H__)furanones, has been developed. The reg

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