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Studies on Fatty Acid-Thionyl Chloride System – Evidence of Side Reaction and the Mechanism of Inhibition in the Acetic Acid-Thionyl Chloride Reaction

✍ Scribed by Singh, H. N.

Publisher
John Wiley and Sons
Year
1971
Weight
302 KB
Volume
73
Category
Article
ISSN
0931-5985

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✦ Synopsis

Acetic acid thionyl chloride reaction was studied in chloro-, bromo-and nitrobenzene. The reaction seems to follow simple course in the beginning, but after some time complications occur. The percentage of hydrogen chloride in the effluent gases was determined by dissolving the gases in water and measuring chloride ion concentration using silver-silver chloride electrode. The percentage of HCl in the effluent was found to increase with increasing dipole moments of solvents. Acetic anhydride and dioxane retard the reaction. Mechanism of the retardation of reaction rate by the product and added dioxane has been discussed.

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