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Sulfonyl Transfer Reactions − A Kinetic Study on the Solvolysis of p-(Dimethylamino)benzenesulfonyl Chloride in Aqueous Acetic Acid

✍ Scribed by Sergio Thea; Corrado Carpanelli; Giorgio Cevasco


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
264 KB
Volume
2001
Category
Article
ISSN
1434-193X

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✍ Franklin P. DeHaan; Paul Y. Ahn; Carl R. Kemnitz; Steven K. Ma; Jim Na; Bimal R. 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 135 KB 👁 3 views

Vacuum line kinetic studies of the reaction of p-toluenesulfonyl chloride and benzene or toluene, using aluminum chloride as the catalyst and dichloromethane as the solvent were determined at 25ЊC by means of gas chromatography. The reaction is first-order in arene, tosyl chloride, and in AlCl 3 as