𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Influence of Substitution and the Effect of Chain-Length on Fatty Acid—Thionyl Chloride Reaction

✍ Scribed by Singh, H. N. ;Beg, M. A.

Publisher
John Wiley and Sons
Year
1968
Weight
270 KB
Volume
70
Category
Article
ISSN
0931-5985

No coin nor oath required. For personal study only.

✦ Synopsis

Kinetic data are reporled for the halogenation of the first five members of the fatty acid series. The influence of substitution of electron withdrawing and electron releasing group in the methyl radical of acetic acid was studied in solution.

The mechanism of the reaction has been discussed.

Uber den EinfluS der Substitution und der Kettenlauge bei der

📜 SIMILAR VOLUMES

Studies on Fatty Acid-Thionyl Chloride S
Studies on Fatty Acid-Thionyl Chloride System – Evidence of Side Reaction and the Mechanism of Inhibition in the Acetic Acid-Thionyl Chloride Reaction
✍ Singh, H. N. 📂 Article 📅 1971 🏛 John Wiley and Sons ⚖ 302 KB 👁 1 views

Acetic acid thionyl chloride reaction was studied in chloro-, bromo-and nitrobenzene. The reaction seems to follow simple course in the beginning, but after some time complications occur. The percentage of hydrogen chloride in the effluent gases was determined by dissolving the gases in water and me

Effect of Degree, Type, and Position of
Effect of Degree, Type, and Position of Unsaturation on the pKa of Long-Chain Fatty Acids
✍ James R. Kanicky; Dinesh O. Shah 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 151 KB

Titration of a series of C(18) fatty acids yields pK(a) values that decrease with an increasing degree of unsaturation in the fatty acid chain. The pK(a) values of stearic, elaidic, oleic, linoleic, and linolenic acids were studied and compared to values of area per molecule in a spread monolayer of

Kinetic studies on the permanganic oxida
Kinetic studies on the permanganic oxidation of amino acids. Effect of the length of amino acid carbon chain
✍ A. Arrizabalaga; F. J. Andrés-Ordax; M. Y. Fernández-Aránguiz; R. Peche 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 126 KB 👁 2 views

The kinetic study of the permanganic oxidation of some amino acids (glycine, L-alanine, L-ϰ-amino-n-butyric acid, L-norvaline, and L-norleucine) has been carried out in buffered acid medium at 1 Ͻ pH Ͻ 3 using a spectrophotometric technique. An autocatalytic effect due to Mn 2ϩ ions was found in all