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Studies on Cobalt(III) Metallosurfactants. Kinetics and Mechanism of Reduction of Cobalt(III) by Iron(II) in Aqueous Acid Medium

โœ Scribed by K. Santhakumar; N. Kumaraguru; S. Arunachalam; M. N. Arumugham


Publisher
Springer
Year
2006
Tongue
English
Weight
296 KB
Volume
31
Category
Article
ISSN
0340-4285

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โœ Roland Schmid; Valentin N. Sapunov ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 737 KB

The electron transfer step of the reduction of Mn(acac)s and Co(acac)s by Fe(I1) in acetonitrile is preceded by the one-ended dissociation of an acac ligand and the formation of a binuclear bridged complex. After the electron transfer has taken place through the bridging ligand, the complex dissocia