Kinetics and mechanism of complex formation betweenO-bondedcis-(diglycinato)bis(ethylenediamine)cobalt(III) and α-cis-(diglycinato) (triethylenetetramine)cobalt(III) with nickel(II) in aqueous medium
✍ Scribed by Nigamananda Das
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 431 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0340-4285
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## Abstract Kinetics of reduction of the surfactant complex ions, __cis__‐chloro/bromo (dodecylamine)bis(ethylenediamine)cobalt(III) by iron(II) in aqueous solution was studied at 303, 308, and 313 K by spectrophotometry method under pseudo‐first‐order conditions, using an excess of the reductant.
## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0–50 (v/v) % MeOH) at 15.0–35.0°C and I = 0.10 mol dm^−3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ · CoOCOCO~2~Ni]^3+^ in wh