Studies of the temporary anion states of unsaturated hydrocarbons by electron transmission spectroscopy
β Scribed by Jordan, Kenneth D.; Burrow, Paul D.
- Book ID
- 121007137
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 993 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0001-4842
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π SIMILAR VOLUMES
The electron affinity trends observed for the title compounds indicate that in 1.4-cyclohexadiene the A, anion state, arismg from electron capture into the out-of-phase combination of the empty ethenic v\* MOs, lies at lower energy than the B,, anion state, correlated with the in-phase combination.
The symmetries of the two low-lying z\* temporary anion states of 1 $cyclohexadiene are studied by electron energy loss and angular distribution measurements. Analysis of the vibrational modes excited by the resonances and the angular distribution of electrons exciting a totally symmetric vibrationa