𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A study of the order of the π* temporary anion states of 1,4-cyclohexadiene by electron scattering

✍ Scribed by T.M. Stephen; P.D. Burrow

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
500 KB
Volume
179
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The symmetries of the two low-lying z* temporary anion states of 1 $cyclohexadiene are studied by electron energy loss and angular distribution measurements. Analysis of the vibrational modes excited by the resonances and the angular distribution of electrons exciting a totally symmetric vibrational mode provide two independent means to confirm that the 'A. anion state lies below the 'B, state.

📜 SIMILAR VOLUMES

Characterization of the temporary π anio
Characterization of the temporary π anion states of 1,4-cyclohexadiene, γ-pyran, 1,4-dioxin and γ-pyrone by electron transmission spectroscopy
✍ Alberto Modelli; Derek Jones; Sandra Rossini; Giuseppe Distefano 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 353 KB

The electron affinity trends observed for the title compounds indicate that in 1.4-cyclohexadiene the A, anion state, arismg from electron capture into the out-of-phase combination of the empty ethenic v\* MOs, lies at lower energy than the B,, anion state, correlated with the in-phase combination.

Electronic structure of benzaldehyde: A
Electronic structure of benzaldehyde: A comparative study of the lowest excited singlet π* ← π and π* ← n states
✍ S. K. Srivastava; P. C. Mishra 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 614 KB

## Abstract VE‐PPP, CNDO/2, and CNDO/s‐CI methods have been used to investigate the electronic spectrum and structure of benzaldehyde. Electronic charge distributions and bond orders in the ground and lowest excited singlet π\* ← π and π\* ← __n__ states of the molecule have been studied. The molec