Electron transmission spectroscopy is utilized to determine the energies of the temporary anions of chlorobenzene and the di-and tri-chlorobenzenes. The ET spectra, the results of a simple model accounting for the resonance and inductive effects of the chlorines, and ab initio calculations all indic
Electron-transmission study of the temporary anion states of substituted pyridines
โ Scribed by A. Modelli; P.D. Burrow
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 904 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0368-2048
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๐ SIMILAR VOLUMES
The symmetries of the two low-lying z\* temporary anion states of 1 $cyclohexadiene are studied by electron energy loss and angular distribution measurements. Analysis of the vibrational modes excited by the resonances and the angular distribution of electrons exciting a totally symmetric vibrationa
Multireference confguration interaction study of potential energy curves for the ground and lowest excited states for dissociative electron attachment are presented for CHCls/CHCl,-, CHBrs/CHBr,-and CHI&XIr systems. Reasonable agreement has been found with available experimental data for electron at
The electron affinity trends observed for the title compounds indicate that in 1.4-cyclohexadiene the A, anion state, arismg from electron capture into the out-of-phase combination of the empty ethenic v\* MOs, lies at lower energy than the B,, anion state, correlated with the in-phase combination.