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Studies in macrolide synthesis: A sequential aldol/glycosylation approach to the synthesis of concanamycin A

โœ Scribed by Ian Paterson; Malcolm D. McLeod

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
311 KB
Volume
36
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Studies in macrolide synthesis: Stereoco
Studies in macrolide synthesis: Stereocontrolled synthesis of a C1๎—ธC13 segment of concanamycin A
โœ Ian Paterson; Malcolm D. McLeod ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 329 KB

The Ct-Ct3 segment 6 of concanamycin A (1) was prepared by a highly stereocontrolled route (87% overall ds) in 16 steps from the ester 9. Key steps are the one-pot aldol/reduction, 8 + 12, and the HWB reaction, 18 + 19 + 6.8 1997 Elsevier Science Ltd.