𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Studies in IVth group organometallic chemistry. VII: Synthesis of some hetero-polymers containing germanium, tin, and lead in the main polymer chain

✍ Scribed by J. G. Noltes; G. J. M. van der Kerk

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
395 KB
Volume
80
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

It has been shown that di‐p‐styrenyl derivatives of germanium, tin, and lead as well as 1,4‐divinylbenzene and 3,9‐divinylspirobi(meta‐dioxan) react with diphenyltin dihydride to yield linear poly‐addition polymers containing tin or tin and germanium or lead in the main polymer chain. The polymeric products have been characterized by infrared spectroscopy, analytical data and molecular weight.

Reactions of triphenyltin hydride and diphenyltin dihydride with mono‐ and di‐p‐styrenyl derivatives of germanium, tin, and lead yielding monomeric compounds containing two and three hydrocarbon‐linked metal atoms, have also been carried out.

📜 SIMILAR VOLUMES

Studies in IVth group organometallic che
Studies in IVth group organometallic chemistry. IX: Synthesis of organosilicon compounds and polymers containing the p-Phenylene Group
✍ J. G. Noltes; G. J. M. van der Kerk 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 539 KB

## Abstract A number of oligomeric __p__‐phenylenesilanes containing 2‐6 silicon atoms per molecule and a series of low molecular weight poly‐__p__‐phenylenesilanes (n = 10‐30) have been prepared by Wurtz‐type condensation reactions involving appropriate combinations of __p__‐chlorophenyl‐ and chlo