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Studies in IVth group organometallic chemistry. IX: Synthesis of organosilicon compounds and polymers containing the p-Phenylene Group

✍ Scribed by J. G. Noltes; G. J. M. van der Kerk

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
539 KB
Volume
81
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

A number of oligomeric p‐phenylenesilanes containing 2‐6 silicon atoms per molecule and a series of low molecular weight poly‐p‐phenylenesilanes (n = 10‐30) have been prepared by Wurtz‐type condensation reactions involving appropriate combinations of p‐chlorophenyl‐ and chloro‐silanes. The polymeric products have been characterized by infrared spectroscopy, analytical and thermogravimetric data, and number‐average molecular weights, the low value of which is presumably caused by participation of the solvent (toluene) in the reaction. The polymers started to lose weight at temperatures varying from 310 to 485°.

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