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Structures of peptides from α-amino acids methylated at the α-carbon,

✍ Scribed by C. Toniolo; M. Crisma; F. Formaggio; C. Valle; G. Cavicchioni; G. Precigoux; A. Aubry; J. Kamphuis

Publisher
Wiley (John Wiley & Sons)
Year
1993
Tongue
English
Weight
923 KB
Volume
33
Category
Article
ISSN
0006-3525

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The lipophilic, chiral, C h -methylated h-amino acid L-(h Me)Aoc (2-methyl-2-amino-octanoic acid) was prepared using a chemo-enzymatic approach. Two series of terminally protected model peptides, from dimer through to hexamer, containing L-(h Me)Aoc in combination with either Gly or Aib, were synthe