Structures of dichloro[(S)-methionine-N,S]platinum(II) and chloro[glycyl-(S)-methioninato-N,N',S]platinum(II) monohydrate
✍ Scribed by Wilson, C. ;Scudder, M. L. ;Hambley, T. W. ;Freeman, H. C.
- Book ID
- 114509082
- Publisher
- International Union of Crystallography
- Year
- 1992
- Tongue
- English
- Weight
- 430 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract A crystal of the title complex [Pt(DMSO)(GT)] (**1a**), where H~2~GT = glyoxylic acid thiosemicarbazone, has been characterized by X‐ray crystallography and its structure has been compared with that of the recently described cytotoxic complex [Pt(DMSO)(GT)]·DMSO (1). The crystal of **1a
Chloro(dimethyl sulfoxide-jS)[(1R,3S)-1,2,2-trimethylcyclopentane-1,3-diamine-j 2 N,N 0 0 0 ]platinum(II) trichloro(dimethyl sulfoxide-jS)platinum(II)
The title compound, [Pt(N~2~S~2~)(C~13~H~13~P)~2~]·CH~2~Cl~2~, contains Pt^II^ in a square-planar coordination. The five-membered PtS~2~N~2~ ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe~2~Ph analogue and one of the