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Structures and mechanism of formation of the HCO2radical and its HCO2+Ion

โœ Scribed by N. M. Ivanova; B. F. Minaev; Z. M. Muldakhmetov

Publisher
SP MAIK Nauka/Interperiodica
Year
1989
Tongue
English
Weight
383 KB
Volume
29
Category
Article
ISSN
0022-4766

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The absorption cross section of the HCO radical at 614.59 nm and the rate constant for HCO+HCO โ†’ H2CO+CO
โœ J.E. Baggott; H.M. Frey; P.D. Lightfoot; R. Walsh ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 587 KB

Using a combination of XeCl exciplex laser flash photolysis of gas-phase glyoxal and formaldehyde and time-resolved cw dye laser absorption at 614.59 nm, we have determined the ratio k,/a for the reaction HCO+HCO-H,CO+CO (1) at 295k2 K. Similar studies involving the 308 nm photolysis of a variety o