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Vibrational spectroscopic study of nickel (II) formate, Ni(HCO2)2, and its aqueous solution

✍ Scribed by H.G.M. Edwards; A. Knowles


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
579 KB
Volume
268
Category
Article
ISSN
0022-2860

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## Abstract The ligand (N^1^‐[3‐(2‐aminoethylimino)‐1,1‐dimethylbutyl]ethane‐1,2‐diamine), L^1^, induces a high ligand field on the central Ni^II^ ion. Thus it is relatively easy to oxidize(Ni^II^L^1^)^2+^. However, the kinetic stability of the Ni^III^L^1^ complexes is considerably lower than that